The synthesis of a pyridine-: N -oxide isophthalamide rotaxane utilizing supplementary amide hydrogen bond interactions

Evans, Nicholas Henley and Gell, Charlie and Peach, Michael Joseph George (2016) The synthesis of a pyridine-: N -oxide isophthalamide rotaxane utilizing supplementary amide hydrogen bond interactions. Organic and Biomolecular Chemistry, 14 (33). pp. 7972-7981. ISSN 1477-0520

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Abstract

The synthesis of a pyridine-N-oxide containing rotaxane, not requiring an additional ionic template, has been achieved in 32% yield. Successful rotaxane formation is dependent upon the structure of the isophthalamide macrocycle used, an observation which has been rationalised by a combination of NMR spectroscopy, X-ray crystallography and computational modelling.

Item Type:
Journal Article
Journal or Publication Title:
Organic and Biomolecular Chemistry
Additional Information:
© Royal Society of Chemistry 2016
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1606
Subjects:
ID Code:
80658
Deposited By:
Deposited On:
02 Aug 2016 07:56
Refereed?:
Yes
Published?:
Published
Last Modified:
09 Apr 2020 02:53