Rapid and simultaneous synthesis of a hydrogen bond template [3]rotaxane and its related [2]rotaxane molecular shuttle

Evans, Nicholas Henley and Akien, Geoffrey Richard (2018) Rapid and simultaneous synthesis of a hydrogen bond template [3]rotaxane and its related [2]rotaxane molecular shuttle. Supramolecular Chemistry, 30 (2). pp. 158-164. ISSN 1029-0478

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Abstract

The rapid preparation and spectroscopic characterisation of a hydrogen bond templated [3]rotaxane and its related [2]rotaxane is presented. VT NMR spectroscopy confirms that the [2]rotaxane acts as a molecular shuttle. DFT computational modelling provides some further insight into the non-covalent interactions present within the rotaxane species.

Item Type:

Journal Article

Journal or Publication Title:

Supramolecular Chemistry

Additional Information:

This is an Accepted Manuscript of an article published by Taylor & Francis in Supramolecular Chemistry on 08/11/2017, available online: http://www.tandfonline.com/10.1080/10610278.2017.1400031

Uncontrolled Keywords:

/dk/atira/pure/subjectarea/asjc/1600/1600

Subjects:

?? self-assemblyrotaxanemolecular shuttlehydrogen bondinggeneral chemistrychemistry(all) ??

ID Code:

88462

Deposited By:

ep_importer_pure

Deposited On:

30 Oct 2017 09:02

Refereed?:

Yes

Published?:

Published

Last Modified:

21 Oct 2024 23:48

URI:

https://eprints.lancs.ac.uk/id/eprint/88462