Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of β-diketones

Montoya, Carmen A. and Gomez, Clara F. and Paninho, Ana B. and Nunes, Ana V.M. and Mahmudov, Kamran T. and Najdanovic, Vesna and Martins, Luisa M.D.R.S. and Guedes da Silva, Fatima C. and Pombiero, Armando J. L. and Nunes da Ponte, Manuel (2016) Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of β-diketones. Journal of Catalysis, 335. pp. 135-140. ISSN 0021-9517

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Abstract

Zinc(II) complexes of arylhydrazones of β-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.

Item Type:

Journal Article

Journal or Publication Title:

Journal of Catalysis

Additional Information:

This is the author’s version of a work that was accepted for publication in Journal of Catalysis. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Catalysis, 335, 2016 DOI: 10.1016/j.jcat.2015.12.027

Uncontrolled Keywords:

/dk/atira/pure/subjectarea/asjc/1500/1503

Subjects:

?? carbon dioxideepoxidestyrene carbonatecyclic carbonateszincarylhydrazone of b-diketonescatalysisphysical and theoretical chemistry ??

Departments:

Faculty of Science and Technology > Engineering

ID Code:

78586

Deposited By:

ep_importer_pure

Deposited On:

09 Mar 2016 13:40

Refereed?:

Yes

Published?:

Published

Last Modified:

18 Sep 2024 00:38

URI:

https://eprints.lancs.ac.uk/id/eprint/78586