Huckerby, Thomas and Dickerson, John and Tai, G.H. and Lauder, Robert and Brown, Gavin and Nieduszynski, Ian (1993) 13C NMR spectroscopy of keratan sulphates : assignments for the reduced form of a repeat unit tetrasaccharide derived from keratan sulphate by a keratanase digestion and partial assignments for two fucosylated pentasaccharides. Magnetic Resonance in Chemistry, 31 (4). pp. 394-398. ISSN 1097-458X
Full text not available from this repository.Abstract
A full assignment of the 60°C 13C NMR spectrum for the reduced form of a repeat unit β-linked tetrasaccharide derived by keratanase digestion from keratan sulphate, GlcNAc(6SO4)β1–3Gal(6SO4)β1–4GlcNAc(6SO4)β1–3-Gal-ol, was achieved via two-dimensional C/H correlation and 1H COSY experiments, and a complete first-order analysis of the 600 MHz proton spectrum. Partial 13C assignments for two fucosylated keratan sulphate pentasc-charides derived using hydrazinolysis and nitrous acid treatment are discussed.