Structural investigation of 1,4-diaminobenzene complexes of nickel and cadmium chloride by FT-IR and Raman spectroscopy.

Ozel, A. E. and Akyüz, S. and Davies, J. E. D. (1995) Structural investigation of 1,4-diaminobenzene complexes of nickel and cadmium chloride by FT-IR and Raman spectroscopy. Journal of Molecular Structure, 348. pp. 77-80.

Abstract

Infrared and Raman (4000-200 cm−1) spectra are reported for 1,4-diaminobenzene complexes of nickel (II) and cadmium (II) chloride, MCl2PPD, where M=Ni or Cd and PPD=1,4-diaminobenzene (p-phenylenediamine). Vibrational spectroscopic investigation indicated that complexes have polymeric structures containing bidentate bridging molecules of 1,4-diaminobenzene.