Divergent Mechanisms for the Skeletal Rearrangement and [2+2] Cycloaddition of Enynes Catalyzed by Gold

Nieto-Oberhuber, Cristina and López, Salomé and Munoz-Herranz, Maria and Cárdenas, Diego J. and Buñuel, Elena and Nevado, Cristina and Echavarren, Antonio M. (2005) Divergent Mechanisms for the Skeletal Rearrangement and [2+2] Cycloaddition of Enynes Catalyzed by Gold. Angewandte Chemie International Edition, 44 (38). pp. 6146-6148. ISSN 1433-7851

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Abstract

Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rearrangement of enynes is supported by DFT calculations and kinetic studies. Cyclobutenes may arise from the corresponding syn-cyclopropylgold(I) carbenes

Item Type:
Journal Article
Journal or Publication Title:
Angewandte Chemie International Edition
Uncontrolled Keywords:
Research Output Funding/yes_externally_funded
Subjects:
?? yes - externally fundedgeneral chemistrycatalysischemistry(all) ??
ID Code:
185738
Deposited By:
Deposited On:
03 Feb 2023 15:15
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Jul 2024 11:59