Nieto-Oberhuber, Cristina and Munoz-Herranz, Maria and López, Salomé and Jiménez-Núñez, Eloísa and Nevado, Cristina and Herrero-Gómez, Elena and Raducan, Mihai and Echavarren, Antonio M. (2006) Gold(I)-Catalyzed Cyclizations of 1,6-Enynes: Alkoxycyclizations andexo/endo Skeletal Rearrangements. Chemistry - A European Journal, 12 (6). pp. 1677-1693. ISSN 0947-6539
Full text not available from this repository.Abstract
Gold(I) complexes are the most active catalysts for the biscyclopropanation of dienynes to form tetracyclic compounds. PtII and ZnII are also able to promote the biscyclopropanation, although less efficiently. The configurations obtained in all cases with the use of gold(I) catalysts can be explained by the pathway proceeding through anti cyclopropyl gold carbenes. Similar intermediates are most probably involved in reactions catalyzed by RuII and PtII. Two different cyclopropanation pathways have been found; they depend on the structures of the cyclopropyl gold carbenes (anti or syn) and the relative arrangements of the metal carbenes and the alkenes.