Evans, Louise A. and Fey, Natalie and Lloyd-Jones, Guy C. and Munoz-Herranz, Maria and Slatford, Paul A. (2009) Cryptocatalytic 1,2-alkene migration in a σ-alkyl palladium diene complex. Angewandte Chemie International Edition, 48 (34). pp. 6262-6265. ISSN 1433-7851
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Official URL: https://doi.org/10.1002/anie.200901468
Abstract
Not so simple: A combination of 2H, 13C, and 108Pd labels shows that the alkene migration in a s-alkyl palladium diene complex induced by trifluoromethanesulfonic acid is not intramolecular or acid-mediated, but instead requires a self-generated palladium hydride species (see scheme; Tf=triflate).
Item Type:
Journal Article
Journal or Publication Title:
Angewandte Chemie International Edition
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1500/1503
Subjects:
?? YES - EXTERNALLY FUNDEDCHEMISTRY(ALL)CATALYSIS ??
ID Code:
185730
Deposited By:
Deposited On:
03 Feb 2023 15:25
Refereed?:
Yes
Published?:
Published
Last Modified:
21 Sep 2023 03:23