Evans, Louise A. and Fey, Natalie and Lloyd-Jones, Guy C. and Munoz-Herranz, Maria and Slatford, Paul A. (2009) Cryptocatalytic 1,2-alkene migration in a σ-alkyl palladium diene complex. Angewandte Chemie International Edition, 48 (34). pp. 6262-6265. ISSN 1433-7851
Full text not available from this repository.Abstract
Not so simple: A combination of 2H, 13C, and 108Pd labels shows that the alkene migration in a s-alkyl palladium diene complex induced by trifluoromethanesulfonic acid is not intramolecular or acid-mediated, but instead requires a self-generated palladium hydride species (see scheme; Tf=triflate).
Item Type:
Journal Article
Journal or Publication Title:
Angewandte Chemie International Edition
Uncontrolled Keywords:
Research Output Funding/yes_externally_funded
Subjects:
?? yes - externally fundedgeneral chemistrycatalysischemistry(all) ??
ID Code:
185730
Deposited By:
Deposited On:
03 Feb 2023 15:25
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Jul 2024 11:59