Transition metal-catalysed intermolecular reaction of allenes with oxygen nucleophiles: A perspective

Muñoz, María Paz (2012) Transition metal-catalysed intermolecular reaction of allenes with oxygen nucleophiles: A perspective. Organic and Biomolecular Chemistry, 10 (18). pp. 3584-3594. ISSN 1477-0520

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Abstract

Transition metal catalysed hydroalkoxylation of allenes has received much attention in recent years, and both the intra- and intermolecular versions have been reported. Gold(I) complexes are among the most active catalysts for these processes. This critical perspective article will cover the progress in this field, analysing the intermolecular metal-catalysed reaction of allenes using palladium, iridium, rhodium, ruthenium, gold and platinum, in the presence of alcohols, water or carboxylic acids, and the mechanistic implications of these processes depending on the metal used.

Item Type:
Journal Article
Journal or Publication Title:
Organic and Biomolecular Chemistry
Uncontrolled Keywords:
Research Output Funding/no_not_funded
Subjects:
?? no - not fundedbiochemistryorganic chemistryphysical and theoretical chemistry ??
ID Code:
185727
Deposited By:
Deposited On:
03 Feb 2023 15:35
Refereed?:
Yes
Published?:
Published
Last Modified:
15 Jul 2024 23:31