Allene-derived gold and platinum complexes: synthesis and first applications in catalysis

Maliszewska, Hanna and Hughes, David and Munoz-Herranz, Maria Paz (2020) Allene-derived gold and platinum complexes: synthesis and first applications in catalysis. Dalton Transactions, 49 (13). pp. 4034-4038. ISSN 1477-9226

Full text not available from this repository.

Abstract

We report here the synthesis, full characterisation and first application in catalysis of novel Au(I), Au(III) and Pt(II) carbene-type complexes formed from bis(pyridyl)allenes. The catalytic activity of the new Au(I)-complexes in the cylisation of 1,6-enynes, benchmark reaction for new Au and Pt complexes, was comparable to Au(I)-state-of-the-art catalysts used in these reactions. Reactions with the new Au(III)- and Pt(II)-complexes ocurred under milder conditions than the reported with AuCl3 and PtCl2.

Item Type:
Journal Article
Journal or Publication Title:
Dalton Transactions
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1604
Subjects:
?? YES - EXTERNALLY FUNDEDNOINORGANIC CHEMISTRY ??
ID Code:
185706
Deposited By:
Deposited On:
03 Feb 2023 16:20
Refereed?:
Yes
Published?:
Published
Last Modified:
02 Nov 2023 11:20