An alkyne hydrosilylation-Hiyama coupling approach to highly functionalised 1,3-dienes

McAdam, C.A. and McLaughlin, M.G. and Cook, M.J. (2015) An alkyne hydrosilylation-Hiyama coupling approach to highly functionalised 1,3-dienes. Organic Chemistry Frontiers, 2 (5). pp. 510-514.

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Abstract

A high yielding and robust protocol for the stereodefined synthesis of 1,3-dienes has been established through a hydrosilylation–Hiyama coupling strategy. In all cases the products were formed as single E,E isomers and conditions are tolerant of a wide range of functional groups not compatible with other methods.

Item Type:
Journal Article
Journal or Publication Title:
Organic Chemistry Frontiers
ID Code:
158603
Deposited By:
Deposited On:
27 Aug 2021 15:35
Refereed?:
Yes
Published?:
Published
Last Modified:
18 Sep 2023 01:57