Fulgheri, T. and Cornwall, P. and Turner, A.R. and Sweeney, J.B. and Gill, D.M. (2019) Parallel Kinetic Resolution of Intramolecular Furan Diels-Alder Cycloadducts via Asymmetric Hydroboration. European Journal of Organic Chemistry, 2019 (43). pp. 7223-7227. ISSN 1434-193X
Full text not available from this repository.Abstract
Simple, parallel and dynamic: asymmetric hydroboration reactions of racemic intramolecular Diels‐Alder furan (IMDAF) cycloadducts give regiodivergent outcomes in which simple, parallel and dynamic kinetic resolutions of the substrate enantiomers may be observed. We report parallel kinetic resolution of intramolecular Diels‐Alder cycloadducts, where up to five stereocentres are defined using asymmetric hydroboration as the enantiodiscriminating reaction, and reveal evidence for dynamic kinetic resolution based on a reversible cycloaddition.