Cantrill, Alex A. and Hall, Lee D. and Jarvis, Ashley N. and Osborn, Helen M.I. and Raphy, Jenny and Sweeney, J. B. (1996) Asymmetric aziridine synthesis via aza-Darzens reaction of bromoacylcamphorsultam. Chemical Communications, 1996 (23). pp. 2631-2632. ISSN 1359-7345
Full text not available from this repository.Abstract
The aza-Darzens reaction of the chiral enolate derived from bromoacetylcamphorsultam 1 with N-(diphenylphosphinyl)aryl- and tert-butyl-methanimines proceeds in good yield to give cis-N-(diphenylphosphinyl)aziridinylcarbonyl sultams with high de. Monochiral cis-aziridinecarboxylates may be obtained in acceptable yield by hydrolysis of these sultams.
Item Type:
Journal Article
Journal or Publication Title:
Chemical Communications
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500/2505
Subjects:
?? materials chemistrysurfaces, coatings and filmsmetals and alloysceramics and compositesgeneral chemistrycatalysiselectronic, optical and magnetic materialschemistry(all) ??
ID Code:
133276
Deposited By:
Deposited On:
30 Apr 2019 11:25
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Jul 2024 11:08