Probing Lewis Acid-Base Interactions in Single-Molecule Junctions

Liu, Xunshan and Li, Xiaohui and Sangtarash, Sara and Sadeghi, Hatef and Decurtins, Silvio and Häner, Robert and Hong, Wenjing and Lambert, Colin and Liu, Shi-xia (2018) Probing Lewis Acid-Base Interactions in Single-Molecule Junctions. Nanoscale, 10 (38). pp. 18131-18134. ISSN 2040-3364

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Abstract

A novel strategy to regulate the tunneling mechanism for charge transport through an organoborane wire via Lewis acid-base interactions has been developed. A change from LUMO- to HOMO-dominated charge transport upon the addition of the fluoride is verified both experimentally and theoretically.

Item Type:
Journal Article
Journal or Publication Title:
Nanoscale
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500
Subjects:
ID Code:
127698
Deposited By:
Deposited On:
27 Sep 2018 10:10
Refereed?:
Yes
Published?:
Published
Last Modified:
24 Nov 2020 06:43