Probing Lewis Acid-Base Interactions in Single-Molecule Junctions

Liu, Xunshan and Li, Xiaohui and Sangtarash, Sara and Sadeghi, Hatef and Decurtins, Silvio and Häner, Robert and Hong, Wenjing and Lambert, Colin and Liu, Shi-xia (2018) Probing Lewis Acid-Base Interactions in Single-Molecule Junctions. Nanoscale, 10 (38). pp. 18131-18134. ISSN 2040-3364

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Abstract

A novel strategy to regulate the tunneling mechanism for charge transport through an organoborane wire via Lewis acid-base interactions has been developed. A change from LUMO- to HOMO-dominated charge transport upon the addition of the fluoride is verified both experimentally and theoretically.

Item Type:

Journal Article

Journal or Publication Title:

Nanoscale

Uncontrolled Keywords:

/dk/atira/pure/subjectarea/asjc/2500/2500

Subjects:

?? general materials sciencematerials science(all) ??

Departments:

Faculty of Science and Technology > Physics

ID Code:

127698

Deposited By:

ep_importer_pure

Deposited On:

27 Sep 2018 10:10

Refereed?:

Yes

Published?:

Published

Last Modified:

16 Jul 2024 10:49

URI:

https://eprints.lancs.ac.uk/id/eprint/127698