Huckerby, Thomas and Dickerson, John and Tai, G.H. and Lauder, Robert and Brown, Gavin and Nieduszynski, Ian (1993) 13C NMR spectroscopy of keratan sulphates : assignments for the reduced form of a repeat unit tetrasaccharide derived from keratan sulphate by a keratanase digestion and partial assignments for two fucosylated pentasaccharides. Magnetic Resonance in Chemistry, 31 (4). pp. 394-398.
Full text not available from this repository.Abstract
A full assignment of the 60°C 13C NMR spectrum for the reduced form of a repeat unit β-linked tetrasaccharide derived by keratanase digestion from keratan sulphate, GlcNAc(6SO4)β1–3Gal(6SO4)β1–4GlcNAc(6SO4)β1–3-Gal-ol, was achieved via two-dimensional C/H correlation and 1H COSY experiments, and a complete first-order analysis of the 600 MHz proton spectrum. Partial 13C assignments for two fucosylated keratan sulphate pentasc-charides derived using hydrazinolysis and nitrous acid treatment are discussed.
| Item Type: | Article |
|---|---|
| Journal or Publication Title: | Magnetic Resonance in Chemistry |
| Uncontrolled Keywords: | Keratan sulphate ; 13C NMR ; C/H correlation ; Oligosaccharides ; Structural assignment |
| Subjects: | Q Science > QH Natural history > QH301 Biology |
| Departments: | Faculty of Science and Technology > Lancaster Environment Centre Faculty of Health and Medicine > Biomedical & Life Sciences VC's Office |
| ID Code: | 34790 |
| Deposited By: | Dr Bob Lauder |
| Deposited On: | 09 Dec 2010 13:53 |
| Refereed?: | Yes |
| Published?: | Published |
| Last Modified: | 26 Jul 2012 17:41 |
| Identification Number: | |
| URI: | http://eprints.lancs.ac.uk/id/eprint/34790 |
Actions (login required)
| View Item |
