Huckerby, Thomas and Dickerson, John and Tai, G.H. and Lauder, Robert and Brown, Gavin and Nieduszynski, Ian (1993) 13C NMR spectroscopy of keratan sulphates : assignments for the reduced form of a repeat unit tetrasaccharide derived from keratan sulphate by a keratanase digestion and partial assignments for two fucosylated pentasaccharides. Magnetic Resonance in Chemistry, 31 (4). pp. 394-398. ISSN 1097-458XFull text not available from this repository.
A full assignment of the 60°C 13C NMR spectrum for the reduced form of a repeat unit β-linked tetrasaccharide derived by keratanase digestion from keratan sulphate, GlcNAc(6SO4)β1–3Gal(6SO4)β1–4GlcNAc(6SO4)β1–3-Gal-ol, was achieved via two-dimensional C/H correlation and 1H COSY experiments, and a complete first-order analysis of the 600 MHz proton spectrum. Partial 13C assignments for two fucosylated keratan sulphate pentasc-charides derived using hydrazinolysis and nitrous acid treatment are discussed.
|Journal or Publication Title:||Magnetic Resonance in Chemistry|
|Uncontrolled Keywords:||Keratan sulphate ; 13C NMR ; C/H correlation ; Oligosaccharides ; Structural assignment|
|Subjects:||Q Science > QH Natural history > QH301 Biology|
|Departments:||Faculty of Science and Technology > Lancaster Environment Centre|
Faculty of Health and Medicine > Biomedical & Life Sciences
|Deposited By:||Dr Bob Lauder|
|Deposited On:||09 Dec 2010 13:53|
|Last Modified:||04 Nov 2015 02:01|
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