Wang, Jinjin and Zeng, Xibai and Zhang, Hao and Li, Yongtao and Zhao, Shizhen and Su, Shiming and Bai, Lingyu and Wang, Yanan and Zhang, Tuo (2018) Effect of Exogenous Phosphate on the Lability and Phytoavailability of Arsenic in Soils. Chemosphere, 196. pp. 540-547. ISSN 0045-6535
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Abstract
The effect of exogenous phosphate (P, 200 mg·kg-1 soil) on the lability and phyto-availability of arsenic (As) was studied using the diffusive gradients in thin films (DGT) technique. Lettuce were grown on the As-amended soils following the stabilization of soil labile As after 90 day’s incubation. Phosphate (P) application generally facilitated plant growth except one grown on P-sufficient soil. Soil labile As concentration increased in all the soils after P application due to a competition effect. Plant As concentration increased in red soils collected from Hunan Province, while decreases were observed in the other soils. Even though, an overall trend of decrease was obtained in As phytoavailability along with the increase of DGT-measured soil labile P/As molar ratio. The functional equation between P/As and As phytoavailability provided a critical value of 1.7, which could be used as a guidance for rational P fertilization, thus avoiding overfertilization.