Zaldi, Nordiyana Binti and Hussen, Rusnah Syahila Duali and Lee, See Mun and Halcovitch, Nathan R. and Jotani, Mukesh M. and Tiekink, Edward R. T. (2017) Secondary bonding in di-methyl-bis-(morpholine-4-carbodi-thio-ato-κ(2)S,S')tin(IV) : crystal structure and Hirshfeld surface analysis. Acta crystallographica. Section E, Crystallographic communications, 73 (6). pp. 842-848. ISSN 2056-9890
Full text not available from this repository.Abstract
The title compound, [Sn(CH3)2(C5H8NOS2)2], has the Sn(IV) atom bound by two methyl groups which lie over the weaker Sn-S bonds formed by two asymmetrically chelating di-thio-carbamate ligands so that the coordination geometry is skew-trapezoidal bipyramidal. The most prominent feature of the mol-ecular packing are secondary Sn⋯S inter-actions [Sn⋯S = 3.5654 (7) Å] that lead to centrosymmetric dimers. These are connected into a three-dimensional architecture via methyl-ene-C-H⋯S and methyl-C-H⋯O(morpholino) inter-actions. The Sn⋯S inter-actions are clearly evident in the Hirshfeld surface analysis of the title compound along with a number of other inter-molecular contacts.