trans-Di-chlorido-bis-(dimethyl sulfoxide-κO)bis-(4-fluoro-benzyl-κC(1))tin(IV):crystal structure and Hirshfeld surface analysis

Amin, Nur Adibah Binti Mohd and Hussen, Rusnah Syahila Duali and Lee, See Mun and Halcovitch, Nathan R. and Jotani, Mukesh M. and Tiekink, Edward R. T. (2017) trans-Di-chlorido-bis-(dimethyl sulfoxide-κO)bis-(4-fluoro-benzyl-κC(1))tin(IV):crystal structure and Hirshfeld surface analysis. Acta crystallographica. Section E, Crystallographic communications, 73 (Pt 5). pp. 667-672. ISSN 2056-9890

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Abstract

The Sn(IV) atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa-hedron. The crystal features C-H⋯F, C-H⋯Cl and C-H⋯π inter-actions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the mol-ecular packing are clearly evident from the analysis of the Hirshfeld surface.

Item Type: Journal Article
Journal or Publication Title: Acta crystallographica. Section E, Crystallographic communications
Uncontrolled Keywords: /dk/atira/pure/subjectarea/asjc/1600
Subjects:
ID Code: 86563
Deposited By: ep_importer_pure
Deposited On: 01 Jun 2017 09:54
Refereed?: Yes
Published?: Published
Last Modified: 17 Feb 2020 03:34
URI: https://eprints.lancs.ac.uk/id/eprint/86563

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