Blue rhenium tricarbonyl DPPZ complexes – low energy charge-transfer absorption at tissue-penetrating wavelengths

Coogan, Michael Peter and Platts, James A. (2016) Blue rhenium tricarbonyl DPPZ complexes – low energy charge-transfer absorption at tissue-penetrating wavelengths. Chemical Communications, 52 (84). pp. 12498-12501. ISSN 1359-7345

Full text not available from this repository.

Abstract

fac-[Re(CO)3(dppz)] complexes of amido ligands generated in situ under basic conditions display an intense (ε = 16460 L mol−1 cm−1) absorption band between 500–700 nm which are assigned to an n(amido,RNH–) → π* (dppz) inter-ligand charge transfer band offering an extraordinarily low energy charge separating absorption with potential for imaging and energy application.

Item Type: Journal Article
Journal or Publication Title: Chemical Communications
Uncontrolled Keywords: /dk/atira/pure/subjectarea/asjc/2500/2504
Subjects:
ID Code: 83551
Deposited By: ep_importer_pure
Deposited On: 09 Dec 2016 13:46
Refereed?: Yes
Published?: Published
Last Modified: 25 Feb 2020 07:46
URI: https://eprints.lancs.ac.uk/id/eprint/83551

Actions (login required)

View Item View Item