Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure

Rebocho, Sílvia and V. M. Nunes, Ana and Najdanovic, Vesna and Barreiros, Susana and Paiva, Alexandre (2017) Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure. Journal of Chemical and Engineering Data, 62 (1). ISSN 0021-9568

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Abstract

The phase equilibrium of the binary system (CO2 + propionic anhydride) was determined experimentally at temperatures of 308, 313, and 323 K and pressures up to 10 MPa. Measurements were carried out in a high-pressure visual cell with variable volume. The experimental data were modeled using the Peng–Robinson equation of state and the Mathias–Klotz–Prausnitz mixing rule. A good correlation was achieved with this model, with a total average absolute deviation of 0.21%.

Item Type:
Journal Article
Journal or Publication Title:
Journal of Chemical and Engineering Data
Additional Information:
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Chemical and Engineering Data, copyright ©2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.jced.6b00595
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600
Subjects:
ID Code:
83373
Deposited By:
Deposited On:
25 Apr 2017 12:34
Refereed?:
Yes
Published?:
Published
Last Modified:
05 Dec 2020 03:52