Solubility of mixtures containing soybean oil, ionic liquid and methanol

Manic, Marina S. and Najdanovic, Vesna (2016) Solubility of mixtures containing soybean oil, ionic liquid and methanol. The Open Chemical Engineering Journal, 10 (Suppl.). pp. 41-49. ISSN 1874-1231

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Abstract

This paper presents data on mutual solubility of the binary (soybean oil + ionic liquid) and ternary (soybean oil + methanol + ionic liquid) systems, where ionic liquid stands for 1-butyl-3-methylimidazolium thiocyanate [C4MIM][SCN] or 1-butyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide [C4MIM][NTf2] or 1-butyl-3-methylimidazolium dicyanamide [C4MIM][DCA] or 1-butyl-3-methylimidazolium hexafluorophosphate [C4MIM][PF6] or 1-butyl-3-methyl imida zolium hydrogensulfate [C4MIM] [HSO4] or 1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [C10MIM][NTf2] or methyltrioctylammonium bis(trifluoromethylsulfonyl)imide [ALIQUAT][NTf2] or methyltrioctylammonium chloride [ALIQUAT][Cl]. Solubilities were determined by the cloud point titration method in the temperature range of 298 K to 343 K. Obtained results suggest that imidazolium based ionic liquids exhibit lower solubility in soybean oil than ionic liquids with the aliquat cation. Thus, aliquat based ionic liquids are good candidate to be used as co-solvents for biphasic (methanol + soybean oil) mixture.

Item Type:
Journal Article
Journal or Publication Title:
The Open Chemical Engineering Journal
Additional Information:
Open-Access License: This is an open access article licensed under the terms of the Creative Commons Attribution-Non-Commercial 4.0 International Public License (CC BY-NC 4.0) (https://creativecommons.org/licenses/by-nc/4.0/legalcode), which permits unrestricted, non-commercial use, distribution and reproduction in any medium, provided the work is properly cited.
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1500
Subjects:
ID Code:
80031
Deposited By:
Deposited On:
13 Jun 2016 10:42
Refereed?:
Yes
Published?:
Published
Last Modified:
25 Sep 2020 02:36