A study of cerium extraction by TBP and TODGA using a rotating diffusion cell

Bromley, Michael A. and Boxall, Colin (2015) A study of cerium extraction by TBP and TODGA using a rotating diffusion cell. Nukleonika, 60 (4). pp. 859-864. ISSN 0029-5922

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Abstract

For the study of the coupled interfacial-mass transfer kinetics of, inter alia, TBP, TODGA, CyMe4-BTBP and CyMe4-BTPhen based solvent extraction processes, a new rotating diffusion cell (RDC) apparatus has been established at Lancaster University. RDC studies of Ce(IV)/TBP and Ce(III)/TODGA extraction systems have been undertaken in order to improve the understanding of the chemical and kinetic processes involved. In each case, an interesting dependency on local hydrodynamics at the solution phase boundary with results suggesting that the organic extractant molecules migrate into the aqueous phase in order to capture Ce.

Item Type:
Journal Article
Journal or Publication Title:
Nukleonika
Additional Information:
© by Colin Boxall. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License. (CC BY-NC-ND 4.0)
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1604
Subjects:
ID Code:
78512
Deposited By:
Deposited On:
04 Mar 2016 09:28
Refereed?:
Yes
Published?:
Published
Last Modified:
02 Dec 2020 02:59