White phosphorus activation by a Th(III) complex

Formanuik, Alasdair and Ortu, Fabrizio and Beekmeyer, Reece and Kerridge, Andrew and Adams, Ralph and Mills, David (2016) White phosphorus activation by a Th(III) complex. Dalton Transactions, 45 (6). pp. 2390-2393. ISSN 1477-9226

[img]
Preview
PDF (Formanuik et al. - 2016 - White phosphorus activation by a Th(III) complex)
Formanuik_et_al._2016_White_phosphorus_activation_by_a_Th_III_complex.pdf - Published Version
Available under License Creative Commons Attribution.

Download (661kB)

Abstract

[Th(Cp′′)3] (Cp′′ = {C5H3(SiMe3)2-1,3}) activates P4 to give [{Th(Cp′′)3}2(μ–η1:η1-P4)] (1), which has an unprecedented cyclo-P4 binding mode. DFT studies were performed on a model of 1 to probe the bonding in this system.

Item Type:
Journal Article
Journal or Publication Title:
Dalton Transactions
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1604
Subjects:
ID Code:
78274
Deposited By:
Deposited On:
17 Feb 2016 09:13
Refereed?:
Yes
Published?:
Published
Last Modified:
27 Sep 2020 02:55