Redox-dependent Franck–Condon blockade and avalanche transport in a graphene–fullerene single-molecule transistor

Lau, Chit Siong and Sadeghi, Hatef and Rogers, Gregory and Sangtarash, Sara and Dallas, Panagiotis and Porfyrakis, Kyriakos and Warner, Jamie and Lambert, Colin J. and Briggs, G. Andrew D. and Mol, Jan A. (2016) Redox-dependent Franck–Condon blockade and avalanche transport in a graphene–fullerene single-molecule transistor. Nano Letters, 16 (1). pp. 170-176. ISSN 1530-6984

Preview

PDF (Redox-dependent Franck-Condon blockade and avalanche transport in a graphene-fullerene single-molecule transistor)
Redox_dependent_Franck_Condon_blockade_and_avalanche_transport_in_a_graphene_fullerene_single_molecule_transistor.pdf - Accepted Version
Available under License Creative Commons Attribution.
Download (4MB)

Abstract

We report transport measurements on a graphene–fullerene single-molecule transistor. The device architecture where a functionalized C60 binds to graphene nanoelectrodes results in strong electron–vibron coupling and weak vibron relaxation. Using a combined approach of transport spectroscopy, Raman spectroscopy, and DFT calculations, we demonstrate center-of-mass oscillations, redox-dependent Franck–Condon blockade, and a transport regime characterized by avalanche tunnelling in a single-molecule transistor.

Item Type:

Journal Article

Journal or Publication Title:

Nano Letters

Additional Information:

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Nano Letters, copyright ©2015 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://http://pubs.acs.org/doi/10.1021/acs.nanolett.5b03434

Uncontrolled Keywords:

/dk/atira/pure/subjectarea/asjc/1500/1502

Subjects:

?? bioengineeringgeneral materials sciencegeneral chemistrymechanical engineeringcondensed matter physicsmaterials science(all)chemistry(all) ??

Departments:

Faculty of Science and Technology > Physics

ID Code:

77773

Deposited By:

ep_importer_pure

Deposited On:

18 Jan 2016 13:36

Refereed?:

Yes

Published?:

Published

Last Modified:

11 Oct 2024 00:14

URI:

https://eprints.lancs.ac.uk/id/eprint/77773