Stereoelectronic control of photophysics : red and yellow axial and equatorial anomers of a rhenium-quinoline complex

Platel, Rachel H. and Coogan, Michael P. and Platts, James A. (2015) Stereoelectronic control of photophysics : red and yellow axial and equatorial anomers of a rhenium-quinoline complex. Dalton Transactions, 44 (26). pp. 11700-11704. ISSN 1477-9226

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Abstract

A novel quinoline-substituted pyrimidine ligand forms two different coloured complexes upon reaction with Re(CO)(5)Br. These compounds display distinct photophysical properties that are dictated by their stereochemistry.