Metallophthalocyanin-ocenes:scandium phthalocyanines with an eta(5)-bound Cp ring

Platel, Rachel H. and Tasso, Thiago Teixeira and Zhou, Wen and Furuyama, Taniyuki and Kobayashi, Nagao and Leznoff, Daniel B. (2015) Metallophthalocyanin-ocenes:scandium phthalocyanines with an eta(5)-bound Cp ring. Chemical Communications, 51 (27). pp. 5986-5989. ISSN 1359-7345

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Abstract

A series of new scandium complexes supported by the phthalocyanine (Pc) ligand have been prepared and structurally characterized. Reaction of ScCl3 with phthalonitrile affords a mixture of PcScCl (1) and unreacted ScCl3, which upon addition of LiCH(SiMe3)(2) yields THF-soluble PcSc(mu-Cl-2) Li(THF)(2) (2). Metathesis with NaCp or LiCp* generates PcSc(eta(5)-C5H5) and PcSc(eta(5)-C5Me5), respectively, which represent the first examples of eta(5)-Cp metal phthalocyanines where the Cp fragment sandwiches the metal centre.

Item Type:
Journal Article
Journal or Publication Title:
Chemical Communications
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500/2504
Subjects:
ID Code:
76957
Deposited By:
Deposited On:
01 Dec 2015 10:22
Refereed?:
Yes
Published?:
Published
Last Modified:
01 Jul 2020 02:27