Topotactic elimination of water across a C-C ligand bond in a dense 3-D metal-organic framework

Yeung, Hamish H. -M. and Kosa, Monica and Griffin, John M. and Grey, Clare P. and Major, Dan T. and Cheetham, Anthony K. and Griffin, John (2014) Topotactic elimination of water across a C-C ligand bond in a dense 3-D metal-organic framework. Chemical Communications, 50 (87). pp. 13292-13295. ISSN 1359-7345

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Abstract

Upon heating, lithium L-malate undergoes topotactic dehydration to form a phase containing the unsaturated fumarate ligand, in which the original 3-D framework remains intact. Insight into this unusual transformation has been obtained by single crystal X-ray diffraction, MAS-NMR, in situ powder X-ray diffraction and DFT calculations.

Item Type:
Journal Article
Journal or Publication Title:
Chemical Communications
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500/2504
Subjects:
ID Code:
75729
Deposited By:
Deposited On:
28 Sep 2015 11:06
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Nov 2020 06:09