Octaselenocyclododecane

Hua, Guoxiong and Griffin, John M. and Ashbrook, Sharon E. and Slawin, Alexandra M. Z. and Woollins, J. Derek (2011) Octaselenocyclododecane. Angewandte Chemie International Edition, 50 (18). pp. 4123-4126. ISSN 1433-7851

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Abstract

The first of its kind? A simple, twelve-membered C-Se heterocycle (see structure; blue C, yellow Se, black H) was obtained by treatment of secondary amines with Woollins' reagent. The ring formation proceeds through diselenoate intermediates and requires a polar solvent like dichloromethane.

Item Type:
Journal Article
Journal or Publication Title:
Angewandte Chemie International Edition
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1600
Subjects:
?? heterocyclesseleniumwoollins reagentx-ray analysisx-ray crystallographyseleniumchemistryringsgeneral chemistrycatalysischemistry(all) ??
ID Code:
75717
Deposited By:
Deposited On:
28 Sep 2015 15:54
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Jul 2024 09:49