A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption

Mowat, John P. S. and Seymour, Valerie R. and Griffin, John M. and Thompson, Stephen P. and Slawin, Alexandra M. Z. and Fairen-Jimenez, David and Dueren, Tina and Ashbrook, Sharon E. and Wright, Paul A. (2012) A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption. Dalton Transactions, 41 (14). pp. 3937-3941. ISSN 1477-9226

Full text not available from this repository.

Abstract

The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.

Item Type:
Journal Article
Journal or Publication Title:
Dalton Transactions
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1604
Subjects:
ID Code:
75712
Deposited By:
Deposited On:
28 Sep 2015 11:05
Refereed?:
Yes
Published?:
Published
Last Modified:
29 Jul 2020 01:38