Mowat, John P. S. and Seymour, Valerie R. and Griffin, John M. and Thompson, Stephen P. and Slawin, Alexandra M. Z. and Fairen-Jimenez, David and Dueren, Tina and Ashbrook, Sharon E. and Wright, Paul A. (2012) A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption. Dalton Transactions, 41 (14). pp. 3937-3941. ISSN 1477-9226
Full text not available from this repository.Abstract
The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.