Evaluation of the performance of different atmospheric chemical transport models and inter-comparison of nitrogen and sulphur deposition estimates for the UK

Dore, A. J. and Carslaw, D. C. and Braban, C. F. and Cain, M. and Chemel, C. and Conolly, C. and Derwent, R. G. and Griffiths, S. J. and Hall, Jane and Hayman, G. and Lawrence, S. and Metcalfe, S. E. and Redington, A. and Simpson, D. and Sutton, M. A. and Sutton, P. and Tang, Y. S. and Vieno, M. and Werner, M. and Whyatt, Duncan (2015) Evaluation of the performance of different atmospheric chemical transport models and inter-comparison of nitrogen and sulphur deposition estimates for the UK. Atmospheric Environment, 119. pp. 131-143. ISSN 1352-2310

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Abstract

An evaluation has been made of a number of contrasting atmospheric chemical transport models, of varying complexity, applied to estimate sulphur and nitrogen deposition in the UK. The models were evaluated by comparison with annually averaged measurements of gas, aerosol and precipitation concentrations from the national monitoring networks. The models were evaluated in relation to performance criteria. They were generally able to satisfy a criterion of ‘fitness for purpose’ that at least 50% of modelled concentrations should be within a factor of two of measured values. The second criterion, that the magnitude of the normalised mean bias should be less than 20%, was not always satisfied. Considering known uncertainties in measurement techniques, this criterion may be too strict. Overall, simpler models were able to give a good representation of measured gas concentrations whilst the use of dynamic meteorology, and complex photo-chemical reactions resulted in a generally better representation of measured aerosol and precipitation concentrations by more complex models. The models were compared graphically by plotting maps and cross-country transects of wet and dry deposition as well as calculating budgets of total wet and dry deposition to the UK for sulphur, oxidised nitrogen and reduced nitrogen. The total deposition to the UK varied by ±22e36% amongst the different models depending on the deposition component. At a local scale estimates of both dry and wet deposition for individual 5 km 5 km model grid squares were found to vary between the different models by up to a factor of 4.

Item Type:
Journal Article
Journal or Publication Title:
Atmospheric Environment
Additional Information:
Date of Acceptance: 03/08/2015 This is the author’s version of a work that was accepted for publication in Atmospheric Environment. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Atmospheric Environment, 119, 2015 DOI: 10.1016/j.atmosenv.2015.08.008
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1900/1902
Subjects:
ID Code:
75574
Deposited By:
Deposited On:
15 Sep 2015 08:30
Refereed?:
Yes
Published?:
Published
Last Modified:
28 May 2020 03:44