Generation of metallosupramolecular polymer gels from multiply functionalized grid-type complexes

Hardy, John G. and Cao, Xiao-yu and Harrowfield, Jack and Lehn, Jean-Marie (2012) Generation of metallosupramolecular polymer gels from multiply functionalized grid-type complexes. New Journal of Chemistry, 36 (3). pp. 668-673. ISSN 1144-0546

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Abstract

A ditopic ligand (1), containing two tridentate bis(acylhydrazone) subunits and bearing both long alkyl chains and hydrogen-bonding groups, has been synthesised. Metal cation binding in the presence of a base leads to hierarchical self-assembly, forming first a neutral [2 x 2] grid-type complex (2) that hierarchically assembles into metallosupramolecular polymer gels in toluene.

Item Type: Journal Article
Journal or Publication Title: New Journal of Chemistry
Uncontrolled Keywords: /dk/atira/pure/subjectarea/asjc/1500/1503
Subjects:
ID Code: 75395
Deposited By: ep_importer_pure
Deposited On: 09 Sep 2015 06:32
Refereed?: Yes
Published?: Published
Last Modified: 01 Jan 2020 09:21
URI: https://eprints.lancs.ac.uk/id/eprint/75395

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