Surface and interfacial interactions of multilayer graphitic structures with local environment

Mazzocco, Riccardo and Robinson, Benjamin and Rabot, Caroline and Delamoreanu, A. and Zenasni, Aziz and Dickinson, James and Boxall, Colin and Kolosov, Oleg (2015) Surface and interfacial interactions of multilayer graphitic structures with local environment. Thin Solid Films, 585. pp. 31-39. ISSN 0040-6090

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Abstract

In order to exploit the potential of graphene in next-generation devices, such as supercapacitors, rechargeable batteries, displays and ultrathin sensors, it is crucial to understand the solvent interactions with the graphene surface and interlayers, especially where the latter may be in competition with the former, in the medium of application deployment. In this report, we combine quartz crystal microbalance (QCM) and ultrasonic force microscopy methods to investigate the changes in the film-substrate and film-environment interfaces of graphene and graphene oxide films, produced by diverse scalable routes, in both polar (deionised water) and non-polar (dodecane) liquid and vapour environments. In polar liquid environments, we observe nanobubble adsorption/desorption on the graphene film corresponding to a surface coverage of up to 20%. As no comparable behaviour is observed for non-polar environment, we conclude that nanobubble formation is directly due to the hydrophobic nature of graphene with direct consequences for electrode structures immersed in electrolyte solutions. The amount of water adsorbed by the graphene films was found to vary considerably from 0.012 monolayers of water per monolayer of reduced graphene oxide to 0.231 monolayers of water per monolayer of carbon diffusion growth graphene. This is supported by direct nanomechanical mapping of the films immersed in water where an increased variation of local stiffness suggests water propagation within the film and/or between the film and substrate. Film thickness calculations performed for QCM, atomic force microscopy topography, Raman spectroscopy and optical transmission measurements, show that due to the turbostratic structures of large area films Raman returns results an order of magnitude lower (1-2 graphene layers) than direct measurement by QCM (46 ± 1 layers).

Item Type:
Journal Article
Journal or Publication Title:
Thin Solid Films
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500/2506
Subjects:
ID Code:
73652
Deposited By:
Deposited On:
18 Jun 2015 05:39
Refereed?:
Yes
Published?:
Published
Last Modified:
01 Jan 2020 09:11