Bucher, Nicolas and Hartung, Steffen and Arkhipova, Maria and Yu, Denis and Kratzer, Philipp and Maas, Gerhard and Srinivasan, Madhavi and Hoster, Harry E. (2014) A novel ionic liquid for Li ion batteries - uniting the advantages of guanidinium and piperidinium cations. RSC Advances, 4 (4). pp. 1996-2003. ISSN 2046-2069
Full text not available from this repository.Abstract
We report on the synthesis and the properties of N,N,N',N'-tetramethyl-N '',N ''-pentamethyleneguanidinium bis(trifluoromethylsulfonyl)imide (PipGuan-TFSI). The cation of this novel ionic liquid combines guanidinium and piperidinium structural elements. We tested it for its viscosity, ion conductivity, and also for its thermal and electrochemical stability. Furthermore, a 0.5 M solution of lithium TFSI in PipGuan-TFSI was tested as an electrolyte for Li-ion batteries. These experiments included cycles of Li deposition/dissolution on stainless steel and (de) intercalation into/from LiFePO4 electrodes. The tests involving LiFePO4 cathodes were performed at various C-rates and temperatures for a better quantitative comparison to other electrolyte systems. We discuss in how far PipGuan-TFSI successfully combines the advantages of guanidinium and piperidinium ionic liquids for battery electrolyte applications.