Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO(2)

Chapman, Adrian O. and Akien, Geoffrey R. and Arrowsmith, Nicholas J. and Licence, Peter and Poliakoff, Martyn (2010) Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO(2). Green Chemistry, 12 (2). pp. 310-315. ISSN 1463-9262

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Abstract

A miniature catalytic reactor has been developed for the oxidation of alcohols with O-2 in supercritical CO2. Particular attention has been given to ensuring good mixing of O-2 and CO2 prior to contact with the substrate. The reactor was optimised using the oxidation of 2-octanol over 5% Pt + 1% Bi on Al2O3 and the mass balance was measured. The reactor was then evaluated for the oxidation of a series of secondary alcohols, and also the primary alcohol, 1-octanol.

Item Type:
Journal Article
Journal or Publication Title:
Green Chemistry
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2300/2310
Subjects:
ID Code:
72451
Deposited By:
Deposited On:
22 Jan 2015 10:14
Refereed?:
Yes
Published?:
Published
Last Modified:
06 May 2020 03:21