Akien, Geoffrey R. and Qi, Long and Horvath, Istvan T. (2012) Molecular mapping of the acid catalysed dehydration of fructose. Chemical Communications, 48 (47). pp. 5850-5852. ISSN 1359-7345
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Official URL: https://doi.org/10.1039/c2cc31689g
Abstract
Several intermediates and different reaction paths were identified for the acid catalysed conversion of fructose to 5-( hydroxymethyl)-2- furaldehyde (HMF) in different solvents. The structural information combined with results of isotopic-labelling experiments allowed the determination of the irreversibility of the three steps from the fructofuranosyl oxocarbenium ion to HMF as well as the analogous pyranose route.
Item Type:
Journal Article
Journal or Publication Title:
Chemical Communications
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500/2504
Subjects:
?? DIMETHYL-SULFOXIDEPYRANOID TAUTOMERSWATERNMRCHEMISTRYMECHANISMDIMETHYLSULFOXIDECELLULOSEBIOFUELSPYRIDINEMATERIALS CHEMISTRYSURFACES, COATINGS AND FILMSMETALS AND ALLOYSCERAMICS AND COMPOSITESCHEMISTRY(ALL)CATALYSISELECTRONIC, OPTICAL AND MAGNETIC MATERIAL ??
ID Code:
72450
Deposited By:
Deposited On:
22 Jan 2015 10:14
Refereed?:
Yes
Published?:
Published
Last Modified:
19 Sep 2023 01:20