Akien, Geoffrey R. and Qi, Long and Horvath, Istvan T. (2012) Molecular mapping of the acid catalysed dehydration of fructose. Chemical Communications, 48 (47). pp. 5850-5852. ISSN 1359-7345
Full text not available from this repository.Abstract
Several intermediates and different reaction paths were identified for the acid catalysed conversion of fructose to 5-( hydroxymethyl)-2- furaldehyde (HMF) in different solvents. The structural information combined with results of isotopic-labelling experiments allowed the determination of the irreversibility of the three steps from the fructofuranosyl oxocarbenium ion to HMF as well as the analogous pyranose route.
Item Type:
Journal Article
Journal or Publication Title:
Chemical Communications
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500/2505
Subjects:
?? dimethyl-sulfoxidepyranoid tautomerswaternmrchemistrymechanismdimethylsulfoxidecellulosebiofuelspyridinematerials chemistrysurfaces, coatings and filmsmetals and alloysceramics and compositesgeneral chemistrycatalysiselectronic, optical and magnetic mater ??
ID Code:
72450
Deposited By:
Deposited On:
22 Jan 2015 10:14
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Jul 2024 09:40