Catalytic decarboxylative alkenylation of enolates

Schroeder, Sybrin and Taylor, Nicholas and Jackson, Paula and Franckevicius, Vilius (2013) Catalytic decarboxylative alkenylation of enolates. Organic Letters, 15 (14). pp. 3778-3781. ISSN 1523-7060

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Abstract

A palladium-catalyzed decarboxylative alkenylation of stabilized enolates has been developed, which gives rise to alkenylated dicarbonyl products from enol carbonates regioselectively with concomitant installation of a quaternary all-carbon center. The broad scope of the reaction has been demonstrated by successfully utilizing a range of enolates and external phenol nucleophiles.

Item Type:
Journal Article
Journal or Publication Title:
Organic Letters
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/aacsb/disciplinebasedresearch
Subjects:
ID Code:
66161
Deposited By:
Deposited On:
22 Aug 2013 08:50
Refereed?:
Yes
Published?:
Published
Last Modified:
30 Sep 2020 05:53