Conjugated microporous poly (aryleneethynylene) networks

Jiang, Jia-Xing and Su, Fabing and Trewin, Abbie and Wood, Colin D. and Campbell, Nell L. and Niu, Hongjun and Dickinson, Calum and Ganin, Alexey Y. and Rosseinsky, Matthew J. and Khimyak, Yaroslav Z. and Cooper, Andrew I. (2007) Conjugated microporous poly (aryleneethynylene) networks. Angewandte Chemie International Edition, 46 (45). pp. 8574-8578. ISSN 1433-7851

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Rigid wiry nets: Conjugated microporous polymer networks are formed by Sonogashira–Hagihara coupling. Although these materials are amorphous, the micropore size and surface area can be controlled by varying the length of the phenyleneethynylene struts (see picture; the network is shown in blue, and one 1,3,5-substituted benzene node and three connected struts are highlighted with C gray and H white).

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Journal Article
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Angewandte Chemie International Edition
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12 Aug 2013 10:57
Last Modified:
22 Nov 2022 00:05