A soft porous organic cage crystal with complex gas sorption behavior

Mitra, Tamoghna and Wu, Xiaofeng and Clowes, Rob and Jones, James T. A. and Jelfs, Kim E. and Adams, Dave J. and Trewin, Abbie and Bacsa, John and Steiner, Alexander and Cooper, Andrew I. (2011) A soft porous organic cage crystal with complex gas sorption behavior. Chemistry - A European Journal, 17 (37). pp. 10235-10240. ISSN 0947-6539

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Abstract

Big softy! A soft porous molecular crystal composed of organic cages exhibits complex multistep gas sorption isotherms (see figure), analogous to those observed in soft porous metal–organic frameworks. Softness is induced by frustrated packing of the cages and structural flexibility leads to kinetic guest trapping.

Item Type:
Journal Article
Journal or Publication Title:
Chemistry - A European Journal
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600
Subjects:
ID Code:
65974
Deposited By:
Deposited On:
12 Aug 2013 10:57
Refereed?:
Yes
Published?:
Published
Last Modified:
22 Apr 2020 02:49