Lanthanide complexes as chiral probes exploiting circularly polarized luminescence

Carr, Rachel and Evans, Nicholas H. and Parker, David (2012) Lanthanide complexes as chiral probes exploiting circularly polarized luminescence. Chemical Society Reviews, 41 (23). pp. 7673-7686. ISSN 0306-0012

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Abstract

Optical probes that provide information about local chirality have been developed based on changes to the circular polarisation of emitted light. Highly emissive complexes of lanthanide ions are ideally suited for CPL spectroscopy and the design criteria for developing such probes are defined, based on a rigorous stereochemical analysis. The perturbation of a dynamically racemic complex may occur either by a change in complex constitution or by non-covalent association. With complexes of enantiopure ligands, perturbation may involve either dynamic helicity inversion or a reversible change in the lanthanide coordination environment.

Item Type: Journal Article
Journal or Publication Title: Chemical Society Reviews
Uncontrolled Keywords: /dk/atira/pure/subjectarea/asjc/1600
Subjects:
ID Code: 65933
Deposited By: ep_importer_pure
Deposited On: 07 Aug 2013 10:31
Refereed?: Yes
Published?: Published
Last Modified: 28 Feb 2020 03:20
URI: https://eprints.lancs.ac.uk/id/eprint/65933

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