A redox-active [3]rotaxane capable of binding and electrochemically sensing chloride and sulfate anions

Evans, Nicholas H. and Serpell, Christopher J. and Beer, Paul D. (2011) A redox-active [3]rotaxane capable of binding and electrochemically sensing chloride and sulfate anions. Chemical Communications, 47 (31). pp. 8775-8777. ISSN 1359-7345

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Abstract

A ferrocene functionalised redox-active [3]rotaxane which contains two interlocked anion recognition sites has been prepared by chloride anion templation. With chloride two equivalents of anion are bound, one in each of the interlocked cavities, while sulfate forms a 1 : 1 stoichimetric sandwich type complex; the rotaxane can also electrochemically sense the two anions in acetonitrile.

Item Type: Journal Article
Journal or Publication Title: Chemical Communications
Uncontrolled Keywords: /dk/atira/pure/subjectarea/asjc/2500/2504
Subjects:
ID Code: 65930
Deposited By: ep_importer_pure
Deposited On: 07 Aug 2013 10:30
Refereed?: Yes
Published?: Published
Last Modified: 25 Feb 2020 07:11
URI: https://eprints.lancs.ac.uk/id/eprint/65930

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