A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology

Evans, Nicholas H. and Serpell, Christopher J. and Beer, Paul D. (2011) A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology. New Journal of Chemistry, 35 (10). pp. 2047-2053. ISSN 1144-0546

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Abstract

A novel rotaxane containing a meta-xylenediamide macrocycle is prepared by a new clipping methodology. Upon anion metathesis to the non-coordinating hexafluorophosphate salt, the rotaxane host system was shown to bind chloride and bromide anions more strongly than the basic oxoanions dihydrogen phosphate and acetate in the competitive solvent system 1:1 CDCl(3):CD(3)OD.

Item Type:
Journal Article
Journal or Publication Title:
New Journal of Chemistry
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1500/1503
Subjects:
ID Code:
65928
Deposited By:
Deposited On:
07 Aug 2013 10:35
Refereed?:
Yes
Published?:
Published
Last Modified:
13 May 2020 02:14