A [2]catenane displaying pirouetting motion triggered by debenzylation and locked by chloride anion recognition

Evans, Nicholas H. and Serpell, Christopher J. and Beer, Paul D. (2011) A [2]catenane displaying pirouetting motion triggered by debenzylation and locked by chloride anion recognition. Chemistry - A European Journal, 17 (28). pp. 7734-7738. ISSN 0947-6539

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Abstract

Chloride locks the rings: Debenzylation of a chloride-templated N-benzyl pyridinium catenane, allows for a 180° “pirouetting” of the rings in the resulting neutral pyridyl catenane (see scheme). The catenane may be returned to its original co-conformation by chloride recognition as evidenced in solution and in the solid state.

Item Type:
Journal Article
Journal or Publication Title:
Chemistry - A European Journal
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600
Subjects:
ID Code:
65925
Deposited By:
Deposited On:
07 Aug 2013 10:43
Refereed?:
Yes
Published?:
Published
Last Modified:
13 May 2020 02:14