Synthesis of cationic 2,4-dimethylpentadienylruthenium complexes.:Crystal Structure of Carbonyl(η4-cyclohexa-1,3-diene)-(η5-2,4-dimethylpenta-2,4-dienyl)ruthenium Tetrafluoroborate

Lumini, Tito and Cox, David and Roulet, Raymond and Chapuis, Gervais and Nicolo, Francesco (1990) Synthesis of cationic 2,4-dimethylpentadienylruthenium complexes.:Crystal Structure of Carbonyl(η4-cyclohexa-1,3-diene)-(η5-2,4-dimethylpenta-2,4-dienyl)ruthenium Tetrafluoroborate. Helvetica Chimica Acta, 73 (7). pp. 1931-1934. ISSN 1522-2675

Full text not available from this repository.

Abstract

The complex [Ru(η5-C7H11)2H]BF4 (C7H11 = 2,4-dimethylpenta-2,4-dienyl) is highly reactive towards two- and six-electron ligands. e.g. giving with CO complex [RuCO(η4-C7H12)(η5-C7H11)]BF4. The 2,4-dimethylpenta-1,3-diene ligand (C7H12) of the latter complex is readily displaced giving, e.g. with excess cyclohexa-1,3-diene (C6H8) complex [RuCO(η4-C6H8)(η5-C7H11)]BF4. These reactions provide a convenient entry into monopentadienylruthenium chemistry.

Item Type:
Journal Article
Journal or Publication Title:
Helvetica Chimica Acta
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1604
Subjects:
ID Code:
64984
Deposited By:
Deposited On:
10 Jun 2013 09:30
Refereed?:
Yes
Published?:
Published
Last Modified:
01 Jan 2020 08:31