Protonated open and half-open ruthenocenes exhibiting agostic interactions with C-H bond rupture involved in the most facile dynamic process

Cox, David and Roulet, Raymond (1989) Protonated open and half-open ruthenocenes exhibiting agostic interactions with C-H bond rupture involved in the most facile dynamic process. Chemical Communications (3). pp. 175-177. ISSN 1359-7345

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Abstract

The cations [Ru(η5-C7H11)2H]+(1), [Ru(η5-C5H5)(η5-C7H11)H]+(2), and [Ru(η5-C7H11)H]+(3) have provided quantitative evidence for the existence of a class of complexes in which rupture of the C–H component of a C–H–M agostic interaction is involved in the lowest energy fluxional processes.

Item Type:
Journal Article
Journal or Publication Title:
Chemical Communications
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/2500/2504
Subjects:
ID Code:
64978
Deposited By:
Deposited On:
10 Jun 2013 09:28
Refereed?:
Yes
Published?:
Published
Last Modified:
01 Jan 2020 08:31