The synthesis of Ru(diene)2P(OMe)3 complexes and the formation of 3:3-octadienediyl or 4-octatriene ligands upon phosphite addition to M(dimethylbutadiene)2CO (M=Fe, Ru).

Cox, David and Roulet, Raymond (1988) The synthesis of Ru(diene)2P(OMe)3 complexes and the formation of 3:3-octadienediyl or 4-octatriene ligands upon phosphite addition to M(dimethylbutadiene)2CO (M=Fe, Ru). Journal of Organometallic Chemistry, 342 (1). pp. 87-95. ISSN 0022-328X

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Abstract

Low temperature addition of P(OMe)3 to Ru/2,3-dimethylbutadiene and Ru/1,3-cyclohexadiene cocondensates yields Ru(diene)2P(OMe)3 complexes. The reactions of the bis(dimethylbutadiene) complexes M(C6H10)CO (M  Fe, Ru) with P(OMe)3 give new complexes containing either η3:η3-octadienediyl or η4-octatriene ligands.

Item Type:
Journal Article
Journal or Publication Title:
Journal of Organometallic Chemistry
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1604
Subjects:
ID Code:
64974
Deposited By:
Deposited On:
10 Jun 2013 09:25
Refereed?:
Yes
Published?:
Published
Last Modified:
01 Jan 2020 08:31