Preparation of Ru(CO)(diene)2 complexes by electron beam evaporation of ruthenium.

Cox, David and Roulet, Raymond (1984) Preparation of Ru(CO)(diene)2 complexes by electron beam evaporation of ruthenium. Helvetica Chimica Acta, 67 (5). pp. 1365-1367. ISSN 1522-2675

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Abstract

Ru-atoms (0.5–1.5 g) have been generated by electron bombardment and, in separate experiments, were co-condensed at 7 K with excess of 2,3-dimethylbutadiene or 1,3- or 1,4-cyclohexadiene. The complexes Ru(CO)(η4-C6H10)2 (1) and Ru(CO)(η4-C6H8)2 (2), respectively, have been isolated in 25–30% yields on warming the condensate under CO.

Item Type:
Journal Article
Journal or Publication Title:
Helvetica Chimica Acta
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1604
Subjects:
ID Code:
64964
Deposited By:
Deposited On:
10 Jun 2013 09:07
Refereed?:
Yes
Published?:
Published
Last Modified:
01 Jan 2020 08:30