Hydrogenation of CO(2)-Expanded Liquid Terpenes: Phase Equilibrium-Controlled Kinetics

Bogel-Lukasik, Ewa and Serbanovic, Ana and Bogel-Lukasik, Rafal and Banet-Osuna, Anna and Najdanovic-Visak, Vesna and da Ponte, Manuel Nunes (2009) Hydrogenation of CO(2)-Expanded Liquid Terpenes: Phase Equilibrium-Controlled Kinetics. In: Gas-expanded liquids and near-critcial media : green chemistry and engineering. ACS Symposium Series . American Chemical Society, MAR, pp. 191-201. ISBN 978-0-8412-6971-2

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Abstract

The hydrogenation of two liquid terpenes, alpha-pinene and limonene, was carried out in the presence of high-pressure carbon dioxide, using carbon-supported Pt catalysts. Phase equilibrium data on terpene + CO(2) + hydrogen were used to interpret the kinetics of hydrogenation in liquid + vapor systems close to the critical lines of the mixtures.

Item Type:
Contribution in Book/Report/Proceedings
Subjects:
?? solventssupercritical carbon-dioxideselective hydrogenationlimoneneco2behaviorpressurealpha-pinenelinaloolcomplexes ??
ID Code:
63052
Deposited By:
Deposited On:
22 Mar 2013 09:32
Refereed?:
Yes
Published?:
Published
Last Modified:
16 Jul 2024 03:08