Determination of chlorine containing species in explosive residues using chip-based isotachophoresis

Prest, Jeff E. and Beardah, Matthew S. and Baldock, Sara J. and Doyle, Sean P. and Fielden, Peter R. and Goddard, Nicholas J. and Brown, Bernard J. Treves (2008) Determination of chlorine containing species in explosive residues using chip-based isotachophoresis. Journal of Chromatography A, 1195 (1-2). 157–163. ISSN 1873-3778

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Abstract

A new method has been developed to allow the determination of the chlorate, chloride and perchlorate anions in inorganic explosive residues to bemadeusing isotachophoresis (ITP). To enable a good separation of these species to be achieved the method involves the use of two complexing agents. Indium(III) is used to allow the determination of chloride whilst using nitrate as the leading ion and -cyclodextrin is used to allow the separation of chlorate and perchlorate. Separations were carried out using a miniaturised poly(methyl methacrylate) (PMMA) separation device. The method was applied to analysing both model samples and actual inorganic explosive containing residue samples. Successful determinations of these samples were achieved with no interference from other anions typically found in inorganic explosive residues. Limits of detection (LOD) for the species of interestwere calculated to be 0.80mgl−1 for chloride, 1.75mgl−1 for chlorate and 1.40mgl−1 for perchlorate.

Item Type:
Journal Article
Journal or Publication Title:
Journal of Chromatography A
Additional Information:
Times Cited: 15 Treves Brown, Bernard/I-3359-2012; Prest, Jeff/L-3089-2013; , Sean/ Treves Brown, Bernard/0000-0001-5696-2944; Prest, Jeff/0000-0001-5307-3949; , Sean/0000-0002-5633-1349 0 15
ID Code:
63033
Deposited By:
Deposited On:
21 Mar 2013 13:16
Refereed?:
Yes
Published?:
Published
Last Modified:
01 Jan 2020 08:21