First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

Buchard, Antoine and Auffrant, Audrey and Ricard, Louis and Le Goff, Xavier F. and Platel, Rachel H. and Williams, Charlotte K. and Le Floch, Pascal (2009) First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands. Dalton Transactions (46). pp. 10219-10222. ISSN 1477-9226

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Abstract

Serendipitous deprotonation of bis(iminophosphoranyl) methanide Nd(III) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd-C single and multiple bonds.

Item Type:
Journal Article
Journal or Publication Title:
Dalton Transactions
Uncontrolled Keywords:
/dk/atira/pure/subjectarea/asjc/1600/1604
Subjects:
ID Code:
62871
Deposited By:
Deposited On:
12 Mar 2013 16:58
Refereed?:
Yes
Published?:
Published
Last Modified:
19 Feb 2020 08:12